 |

 Below you find a list of the publications of the group over the last
years.
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2005 |
| Authors |
A. Fernández-Ramos and D. G. Truhlar |
| Title |
A New Algorithm for Efficient Direct Dynamics Calculations of
Large-Curvature Tunneling and Its Application to Radical Reactions with 9-15 Atoms |
| Ref. |
Journal of Chemical Theory and Computation 1, 1063-1078 (2005) |
| Authors |
Z. Smedarchina, A. Fernández-Ramos and W. Siebrand |
| Title |
Tunneling dynamics of double proton transfer in formic acid and benzoic acid dimers |
| Ref. |
Journal of Chemical Physics 122, 134309/1-134309/12 (2005) |
| Authors |
E. Martínez-Núñez, A. Fernández-Ramos, S. A. Vázquez, J. M. C. Marques, M. Xue and W. L. Hase |
| Title |
Quasiclassical dynamics simulation of the
collision induced dissociation of Cr(CO)6+ with Xe |
| Ref. |
Journal of Chemical Physics 123, 154311/1-154311/9 (2005) |
| Authors |
E. Martínez-Núñez, S. A. Vázquez, F. J. Aoiz, J. F. Castillo |
| Title |
Quasiclassical trajectory study of the collision-induced
dynamics of Ar+CH3SH+ using an ab initio interpolated potential energy surface |
| Ref. |
Journal of Physical Chemistry A ASAP (2005) |
| Authors |
J. F. Castillo, F. J. Aoiz, L. Bañares, E. Martínez-Núñez, A. Fernández-Ramos and S. A. Vázquez |
| Title |
Quasiclassical trajectory study of the
F+CH4 reaction dynamics on a dual-level interpolated potential energy surface |
| Ref. |
Journal of Physical Chemistry A 109, 8459-8470 (2005) |
| Authors |
E. Martínez-Núñez, S. A. Vázquez, G. Granucci, M. Persico and C. M. Estévez |
| Title |
Photodissociation of formic acid: A trajectory
surface hopping study |
| Ref. |
Chemical physics letters 412, 35-40 (2005) |
| Authors |
J. M. C. Marques, E. Martínez-Núñez, A. Fernández-Ramos and S. A. Vázquez |
| Title |
Trajectory dynamics study of the Ar+CH4 dissociation reaction
at high temperatures: the importance of zero-point-energy effects |
| Ref. |
Journal of physical chemistry A 109, 5415-5423 (2005) |
| Authors |
I. Borges, A. B. Rocha, E. Martínez-Núñez and S. A. Vázquez |
| Title |
Theoretical investigations on the vibronic coupling
between the electronic states S0 and S1 of formic acid including the photodissociation at 248 nm |
| Ref. |
Chemical physics letters 407, 166-170 (2005) |
| Authors |
E. Martínez-Núñez and S. A. Vázquez |
| Title |
Quasiclassical trajectory calculations
on the photodissociation of CF2CHCl at 193 nm: product
energy distributions for the HF and HCl eliminations |
| Ref. |
Journal of chemical physics 122, 104316/1-104316/7 (2005) |
| Authors |
E. Martínez-Núñez, S. A. Vázquez, I. Borges Jr., A. B. Rocha, C. M. Estevez, J. F. Castillo and F. J. Aoiz |
| Title |
On the conformational memory in the photodissociation
of formic acid |
| Ref. |
Journal of Physical Chemistry A 109, 2836-2838 (2005) |
|
|
2004 |
| Authors |
E. Martínez-Núñez and S. A. Vázquez |
| Title |
Rovibrational distributions of HF in
the photodissociation of vinyl fluoride at 193 nm: A direct
MP2 quasiclassical trajectory study |
| Ref. |
Journal of Chemical Physics 121, 5179-5182 (2004) |
| Authors |
E. Martínez-Núñez, S. A. Vázquez and
J. M. C. Marques |
| Title |
Quasiclassical trajectory study of
the collision-induced dissociation of CH3SH+
+ Ar |
| Ref. |
Journal of Chemical Physics 121, 2571-2577 (2004) |
| Authors |
J. González-Vázquez, E.
Martínez-Núñez, S. A. Vázquez, J. Santamaría and L.
Bañares |
| Title |
RRKM and MP2/6-31G(d,p)
quasiclassical trajectory study of the H2
elimination in the photodissociation of vinyl chloride at
193 nm |
| Ref. |
Chemical Physics Letters 396, 442-447 (2004) |
| Authors |
E. Martínez-Núñez, S. A. Vázquez, F.
J. Aoiz, L. Bañares and J. F. Castillo |
| Title |
Further investigation of the HCl
elimination in the photodissociation of vinyl chloride at
193 nm. A direct MP2/6-31G(d,p) trajectory study |
| Ref. |
Chemical Physics Letters 386, 225-232
(2004) |
| Authors |
J. R. Roscioli, Z. Smedarchina, D. Pratt, W. Siebrand and A. Fernández-Ramos |
| Title |
Proton transfer dynamics via high resolution spectroscopy in the gas pahase and instanton calculations |
| Ref. |
Journal of Chemical Physics 120, 11351-11354 (2004) |
| Authors |
Z. Smedarchina, W. Siebrand, A. Fernández-Ramos and E. Martinez-Núñez |
| Title |
New interpretation of ground- and excited-state tunneling splitting in 2-pyridone.2-hydroxypyridine |
| Ref. |
Chemical Physics Letters 386, 396-402 (2004) |
|
|
2003 |
| Authors |
E. Martinez-Núñez, A. Fernández-Ramos, M. N. D. S. Cordeiro, S. A. Vázquez, F. J. Aoiz and L. Bañares |
| Title |
A direct classical trajectory study of the acetone photodissociation on the triplet surface |
| Ref. |
Journal of Chemical Physics 119, 10618-10625 (2003) |
| Authors |
M. N. D. S. Cordeiro, E. Martinez-Núñez, A. Fernández-Ramos and S. A. Vázquez |
| Title |
Direct dynamics study of the photodissociation of triplet propanal at threshold |
| Ref. |
Chemical Physics Letters 381, 37-44 (2003) |
| Authors |
E. Martinez Núñez, A. Fernández-Ramos, S. A. Vázquez, F. J. Aoiz and L. Bañares |
| Title |
A direct classical trajectory study of HCl elimination from the 193 nm photodissociation of vinyl chloride |
| Ref. |
Journal of Physical Chemistry A 107, 7611-7618 (2003) |
| Authors |
T.-S. Ho, H. Rabitz, F. J. Aoiz, L. Bañares, S. A. Vázquez and L. B. Harding |
| Title |
Implementation of a fast analytic ground state potential energy surface for the N(2D)+H2 reaction |
| Ref. |
Journal of Chemical Physics 119, 3063-3070 (2003) |
| Authors |
L. Banares, F. J. Aoiz, S. A. Vázquez, T.-S. Ho and H. Rabitz |
| Title |
Quasi-classical trajectory calculations on a fast analytic potential energy surface for the C(1D)+H2 reaction |
| Ref. |
Chemical Physics Letters 374, 243-251 (2003) |
| Authors |
M. N. D. S. Cordeiro, E. Martínez-Núñez, A. Fernández-Ramos and S. A. Vázquez |
| Title |
A direct DFT dynamics study of the photodissociation of triplet acetaldehyde |
| Ref. |
Chemical Physics Letters 375, 591-597 (2003) |
| Authors |
S. A. Vázquez, F.J. Aoiz, L. Bañares, J. Santamaría, E. Martínez-Núñez and A. Fernández-Ramos |
| Title |
Quasi-classical trajectory study of H2 elimination in the photodissociation of difluoethylenes at 193 nm |
| Ref. |
J. Chem. Phys. 118, 6941-6945 (2003) |
| Authors |
A. Fernández-Ramos, E. Martínez-Núñez, J. M. C. Marques and S. A. Vázquez |
| Title |
Dynamics calculations for the Cl+C2H6 abstraction reaction: thermal rate constants and kinetic isotope effects |
| Ref. |
J. Chem. Phys. 118, 6280-6288 (2003) |
| Authors |
E. Martínez-Núñez, A. Fernández-Ramos, A. Peña-Gallego and S. A. Vázquez |
| Title |
Product energy distributions from ethylene photodissociation at 193 nm: a DFT direct classical trajectory study |
| Ref. |
Chem. Phys. Lett. 369, 1-7 (2003) |
| Authors |
J. González-Vázquez, A. Fernández-Ramos, E. Martínez-Núñez and S. A. Vázquez |
| Title |
Dissociation of difluoroethylenes. I. Global potential energy surface, RRKM and VTST calculations |
| Ref. |
J. Phys. Chem. A, 107, 1389-1397 (2003) |
| Authors |
J. González-Vázquez, E. Martínez-Núñez, A. Fernández-Ramos and S. A. Vázquez |
| Title |
Dissociation of difluoroetylenes. II. Direct classical trajectory study of the HF elimination from 1,2-difluoroethylenes |
| Ref. |
J. Phys. Chem. A, 107, 1398-1404 (2003) |
| Authors |
Z. Smedarchina, W. Siebrand, A. Fernández-Ramos and Q. Cui |
| Title |
Kinetic isotope effects for concerted multiple proton transfer: a direct dynamics study of an active-site model of carbonic anhydrase II |
| Ref. |
J. Am. Chem. Soc. 125, 243-251 (2003) |
|
|
2002 |
| Authors |
E. Martinez-Núñez, J. R. Flores and F. J. Gómez |
| Title |
The dynamics of the energized SC3H radical: A theoretical study of the S+lC3H reaction |
| Ref. |
Femtochemistry and Femtobiology: Ultrafast dynamics in molecular sciences; A. Douhal, J. Santamaria Eds., World Scientific (Singapore), ISBN: 981-02-4866-0 (2002) |
| Authors |
E. Martinez-Núñez, I Borges, Jr and S. A. Vázquez |
| Title |
Association rate constants for the CH3O+NO-->CH3ONO* reaction by classical trajectory and CVTST calculations |
| Ref. |
Journal of Physical Organic Chemistry 15, 123-129 (2002) |
| Authors |
E. Martínez-Núñez, A. Fernández-Ramos, S. A. Vázquez and M. A. Ríos |
| Title |
Rate constants and kinetic isotope effects for the Cl + CH4 --> ClH + CH3. A comparison between LSC-IVR and statistical theories |
| Ref. |
Chem. Phys. Lett. 360, 59-64 (2002) |
| Authors |
A. Fernández-Ramos and M. Zgierski |
| Title |
Theoretical study of the rate constants and kinetic isotope effects of the 1,2-Hydrogen shift of methoxyl and benzyloxyl radicals assisted by water |
| Ref. |
J. Phys. Chem. A 106, 10578-10583 (2002) |
| Authors |
E. Martínez-Núñez, S. A. Vázquez and A. J. C. Varandas |
| Title |
Unimolecular reaction dynamics of HSO. Further analysis of the influence of different barrier samplings on the product energy distributions |
| Ref. |
Phys. Chem. Chem. Phys. 4, 279-287 (2002) |
| Authors |
Z. Smedarchina and A. Fernández-Ramos |
| Title |
Extremal path approach to rate constant calculations by the linearized semiclassical initial value representation |
| Ref. |
J. Chem. Phys. 117, 6022-6031 (2002) |
| Authors |
J. R. Flores, E. Martínez-Núñez, S. A. Vázquez and F. J. Gómez |
| Title |
A Theoretical Study of the Dynamics of the S + c-C3H Reaction |
| Ref. |
Journal of Physical Chemistry A 106, 8811-8819 (2002) |
| Authors |
A. Fernández-Ramos, D. G. Truhlar, J. C. Corchado and J. Espinosa-García |
| Title |
Interpolated algorithm for large curvature tunneling calculations |
| Ref. |
J. Phys. Chem. A. 106, 4957-4960 (2002) |
| Authors |
A. Pena-Gallego, E. Martínez-Núñez and S. A.Vázquez |
| Title |
Dissociation of ethylene and several deuterated derivatives at 193 and 157 nm by direct classical trajectories |
| Ref. |
Chemical Physics Letters 353, 418-425 (2002) |
| Authors |
A. Fernández-Ramos and A. J. C. Varandas |
| Title |
A VTST study of the H+O3 and O+HO2 reactions using a six-dimensional DMBE potential energy surface for ground state HO3 |
| Ref. |
J. Phys. Chem. A 106, 4077-4083 (2002) |
| Authors |
M. Zgierski A. Fernández-Ramos and A. Grabowska |
| Title |
Theoretical study of excited state proton transfer in 3,6-bis(benzoxazolyl)-pyrocatechol (BBPC) |
| Ref. |
J. Chem. Phys. 116, 7486-7494 (2002) |
| Authors |
S. Bakalova, W. Siebrand, A. Fernández-Ramos, Z. Smedarchina and D. D. Petkov |
| Title |
Theoretical study of a model for RNA solvolysis catalyzed by large ribozymes |
| Ref. |
J. Phys. Chem. B 106, 1476-1480 (2002) |
| Authors |
L. Gorb, Y. Podolyan, J. Leszczynsky, W. Siebrand, A. Fernández-Ramos and Z. Smedarchina |
| Title |
A quantum-dynamics study of the prototropic tautomerism of guanine and its contribution to spontaneous point mutations in Escherichia coli |
| Ref. |
Biopolymers 61, 77-83 (2002) |
|
|
2001 |
| Authors |
E. Martinez-Núñez and A. J. C. Varandas |
| Title |
Single-valued potential energy surface for HSO: a distributed polynomial approach |
| Ref. |
Journal of Physical Chemistry A 105, 5923-5932 (2001) |
| Authors |
E. Martinez-Núñez, A. Peña-Gallego and S. A. Vazquez |
| Title |
The unimolecular dissociation of the propionyl radical. A classical dynamics study |
| Ref. |
Journal of Chemical Physics 114, 3546-3553 (2001) |
| Authors |
A. Fernández Ramos, Z. Smedarchina and F. Pichierri |
| Title |
Proton tunneling in calix[4]arenes: a theoretical investigation |
| Ref. |
Chem. Phys. Lett. 343, 627-632 (2001) |
| Authors |
A. Fernández Ramos, E. Martínez Núñez, Z. Smedarchina and S. Vázquez |
| Title |
Rate constants and isotope effects for the CH3 + H2 -> CH4 + H reaction by an approximate semiclassical initial value representation method |
| Ref. |
Chem. Phys. Lett. 341, 351-357 (2001) |
| Authors |
Z. Smedarchina, A. Fernández-Ramos and W. Siebrand |
| Title |
DOIT: A program to calculate thermal rate constants and mode-specific tunneling splittings directly from quantum-chemical calculations |
| Ref. |
J. Comp. Chem. 22, 787-801 (2001) |
| Authors |
E. Martínez-Núñez, C. M. Estévez, J. R. Flores and S. A. Vázquez |
| Title |
Product energy distributions in the HF elimination from 1,1-difluoroetylene. A direct dynamics study |
| Ref. |
Chem. Phys. Lett. 348, 81-88 (2001) |
| Authors |
A. Fernández-Ramos, Z. Smedarchina, W. Siebrand and M. Zgierski |
| Title |
Dynamics of the water-catalyzed phototautomerization of 7-azaindole |
| Ref. |
J. Chem. Phys. 114, 7518-7526 (2001) |
| Authors |
E. Marínez-Núñez, J. M. C. Marques and S. A. Vázquez |
| Title |
A Direct Dynamics Study of the H 2 Elimination from 2,5-Dihydrofuran |
| Ref. |
J. Chem. Phys. A 115 , 7872-7880 (2001) |
| Authors |
A. Fernández-Ramos, Z. Smedarchina and J. Rodríguez-Otero |
| Title |
Double proton transfer in the complex of acetic acid with methanol: Theory vs experiment |
| Ref. |
J. Chem. Phys. 114, 1567-1574 (2001) |
| Authors |
E. Marínez-Núñez and S. A. Vázquez |
| Title |
Anharmonic Quasiclassical Barrier Samplings In Trajectory Calculations and Their Influence on the Product Energy Distributions |
| Ref. |
J. Phys. Chem. A 20 , 4808-4813 (2001) |
| Authors |
A. Fernández-Ramos and D. G. Truhlar |
| Title |
Improved algorithm for corner-cutting tunneling calculations |
| Ref. |
J. Chem. Phys. 114, 1491-1496 (2001) |
|
|
2000 |
| Authors |
A. Fernández-Ramos, Z. Smedarchina, W. Siebrand and M. Zgierski |
| Title |
A direct-dynamics study of the zwitterion-to-neutral interconversion of glycine in aqueous solution |
| Ref. |
J. Chem. Phys. 113, 9714-9721 (2000) |
| Authors |
E. Martínez-Núñez and S. A. Vázquez |
| Title |
Three-center vs. Four-center HF Elimination From Vinyl Fluoride: A Direct Dynamics Study |
| Ref. |
Chem. Phys. Lett. 332, 583-590 (2000) |
| Authors |
A. Fernández-Ramos, Z. Smedarchina and M. Zgierski |
| Title |
Direct-dynamics approach to catalytic effects: the tautomerization of 3-hydroxy-isoquinoline as a test case |
| Ref. |
J. Chem. Phys. 113, 2662-2670, (2000) |
| Authors |
E. Martínez-Núñez, A. Peña-Gallego, R. Rodríguez-Fernández and S.A. Vázquez |
| Title |
Direct Dynamics Simulation of the Methanethiol Cation Decomposition |
| Ref. |
Chem. Phys. Lett. 324, 88-94 (2000) |
| Authors |
A. Peña Gallego, E. Martínez-Núñez and S.A. Vázquez |
| Title |
Dynamics of the Cis-Trans Isomerization and Cl - O Dissociation of Chlorine Nitrite. Classical Trajectory and Statistical Calculations |
| Ref. |
Phys. Chem. Chem. Phys. 2 , 5393-5399 (2000) |
| Authors |
Z. Smedarchina, W. Siebrand , A. Fernández-Ramos, L. Gorb and J. Leszczynsky |
| Title |
A direct-dynamics study of proton transfer through water bridges in guanine and 7-azaindole |
| Ref. |
J. Chem. Phys. 112, 566-573 (2000) |
| Authors |
E. Martínez-Núñez and S.A. Vázquez |
| Title |
Rotational Effects in the Unimolecular Dissociation of the Acetyl Radical |
| Ref. |
Chem. Phys. Lett. 316, 471-476 (2000) |
|
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1999 |
| Authors |
A. Fernández-Ramos, Z. Smedarchina, W. Siebrand, M. Zgierski y M. A. Ríos |
| Title |
Direct-dynamics approaches to proton tunneling rate constants: A comparative test for molecular inversions and an application to 7-azaindole tautomerization |
| Ref. |
J. Am. Chem. Soc. 121, 6280-6289 (1999) |
| Authors |
E. Martínez-Núñez and S.A. Vázquez |
| Title |
Further Dynamical Studies of the Dissociation and Elimination Channels in the Decomposition of Methyl Nitrite |
| Ref. |
J. Chem. Phys. 111, 10501-10510 (1999) |
| Authors |
W. Siebrand, Z. Smedarchina, M. Zgierski and A. Fernández-Ramos |
| Title |
Proton tunnelling in polyatomic molecules: a direct-dynamics instanton approach |
| Ref. |
Int. Rev. Phys. Chem. 18, 5-41 (1999) |
| Authors |
E. Martínez-Núñez and S.A. Vázquez |
| Title |
Classical Dynamics Study of the Unimolecular Decomposition of CH 3 SH + |
| Ref. |
J. Phys. Chem. A 103, 9783-9793 (1999) |
| Authors |
E. Martínez-Núñez and S.A. Vázquez |
| Title |
A Statistical Study of the Methyl Nitrite Isomerization Reaction: Inverse Secondary Isotope Effects |
| Ref. |
Chem. Phys. Lett. 310, 209-214 (1999) |
| Authors |
A. Peña-Gallego, E. Martínez-Núñez and S.A. Vázquez |
| Title |
Nonstatistical Effects in the Unimolecular Dissociation of the Acetyl Radical |
| Ref. |
J. Chem. Phys. 110, 11323-11333 (1999) |
|
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1998 |
| Authors |
A. Fernández-Ramos, E. Martínez-Núñez, M. A. Ríos, J. Rodríguez-Otero, S. Vázquez and C. M. Estévez |
| Title |
Direct dynamics study of the dissociation and elimination channels in the thermal decomposition of methyl nitrite |
| Ref. |
J. Am. Chem. Soc. 120, 7594-7601 (1998) |
| Authors |
A. Peña-Gallego, E. Martínez-Núñez and S.A. Vázquez |
| Title |
Classical Trajectory Study of the Cis-Trans Isomerization and F-O Dissociation of FONO |
| Ref. |
J. Phys. Chem. A 102, 8708-8715 (1998) |
| Authors |
A. Fernández-Ramos, Z. Smedarchina, M. Zgierski and W. Siebrand |
| Title |
Mode-specific tunneling splittings in 9-hydroxyphenalenone: Comparison of two methods for direct tunneling dynamics |
| Ref. |
J. Chem. Phys. 109, 1004-1013 (1998) |
| Authors |
E. Martínez-Núñez and S.A. Vázquez |
| Title |
Dynamical Study of the Dissociation and Elimination Channels in the Decomposition of Methyl Nitrite |
| Ref. |
J. Chem. Phys. 109, 8907-8919 (1998) |
| Authors |
A. Fernández-Ramos, J. Rodríguez-Otero and M. A. Ríos |
| Title |
High level and dual level direct dynamics in the intramolecular proton transfer of hydrogenoxalate anion. Influence of tunneling and isotopic effect |
| Ref. |
J. Phys. Chem. A 102, 2954-2961 (1998) |
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